A new direct band gap silicon allotropeο-Si32

Silicon is a preferred material in solar cells,and most of silicon allotropes have an indirect band gap.Therefore,it is important to find new direct band gap silicon.In the present work,a new direct band gap silicon allotrope of o-Si32 is discovered.The elastic constants,elastic anisotropy,phonon spectra,and electronic structure of o-Si32 are obtained using first-principles calculations.The results show that o-Si32 is mechanically and dynamically stable and is a direct semiconductor material with a band gap of 1.261 e V.     

Three-weight linear codes from Weil sums

Journal of Algebraic Combinatorics - By appropriately choosing a defining set, we define a class of linear codes and establish their complete weight enumerators and weight enumerators using Weil...     

蛋白质-多糖复合体系在活性物质传递中的应用

蛋白质-多糖复合体系作为生物活性物质传递系统的壁材,有着人工合成聚合物或无机物等其他材料不可比拟的多重优势。本文就蛋白质和多糖之间的连接方式及蛋白质-多糖复合体系形成传递系统的多种形式进行了综述,以及对此领域的发展趋势进行了展望。结合蛋白质和多糖的结构特点,二者之间的链接方式分为非共价结合的物理共聚,和共价结合的美拉德偶联、化学交联、酶催化交联等方式,文中分别对各种连接方式的原理和机理,以及其影响因素做了深入阐述。以蛋白质-多糖复合体系为壁材对活性物质的传递形式大体上分成乳化系统、胶束、纳米凝胶、分子复合物以及壳核结构等系统。不同的活性物质的特征和传递需求,可针对性地选择合适结构的蛋白质和多糖种类以及二者的连接方式和传递系统的形式。并且,随着研究的逐步发展和推进,此领域的发展趋势朝着智能化和靶向性的方向进行。目前活性物质的蛋白质-多糖复合体系的传递系统,还依然面临着系统设计、评价和应用等多方面的挑战,这就要求我们在更全面更深入了解认识其对活性物质影响和功效的基础上,安全合理地设计和深入细致地评价活性成分的传递系统。     

Adsorption of Th(IV) from aqueous solution by the graphene oxide nanoribbons/chitosan composite material

Journal of Radioanalytical and Nuclear Chemistry - In order to reduce the potential toxicity to the environment after treatment of radioactive waste water, an eco-friendly graphene oxide...     

胶体晶体自组装常用方法的研究进展

胶体自组装是制造大面积胶体晶体的高效方法,对制备各种功能胶体晶体材料具有十分重要的意义,在微纳制造、新材料、能源、医学等领域有巨大的应用潜力.对胶体自组装过程中涉及的各种作用力进行了详细分析,归纳了胶体晶体自组装的基本方法.面向制造大面积胶体晶体,阐述了几类代表性的新型胶体晶体自组装方法,包括温度辅助、模板辅助、表面活性剂辅助、旋涂法与界面转移相结合等,分析了不同方法的影响因素、优缺点和未来的改良方向,并介绍了在完整单层膜基础上制造三维胶体晶体的工艺方法.为提高胶体晶体制造质量和效率、拓宽胶体自组装技术的应用提供必要参考.     

Intercalated kaolinite as an emerging platform for cancer therapy

An innovative cancer therapy strategy regarding the interface engineering of kaolinite has been designed. The exposed silanol group facilitates more guest species with high dispersion on the supports. Mn_3O_4 magnetic nanoparticles are uniformly distributed on external surfaces of the Kaolin_(C12N)with the Al–O–Mn bond for the detection of the tumor microenvironment by T1-MRI; Doxorubicin(DOX) are loaded in the interlayer space with the electrostatic interaction for chemo-treating; and KI is coated on the outer layer of the nanocomposites based on the electrostatic interaction for thyroid cancer targeting. The synergetic effects and the treatment mechanism enhanced by the interface engineering, KI@DOX-Mn_3O_4-Kaolin_(C12N)can cause remarkably low cell viability(57%, 200 μg/mL), tumor shrinking(75%, 20 μg/kg), and accumulation into the tumor tissues. The novel kaolinite based drug delivery system is expected to incorporate imaging diagnosis, targeted therapy and drug delivery into one single system for postoperative residual thyroid cancer treatment and observation for metastasis of focal area.     

Athermal and Soft Multi-Nanopatterning of Azopolymers: Phototunable Mechanical Properties

Imprinting nanopatterns on flexible substrates has diverse applications in advanced fabrication. However, the traditional thermal nanoimprint lithography (T-NIL) often causes shrinkage upon cooling. Here, a simple yet versatile method is introduced to fabricate multiple nanopatterns on a flexible substrate coated with an azopolymer by combining athermal nanoimprint lithography (AT-NIL) and photolithography. The azopolymer has various mechanical properties upon photoirradiation: 1) phototunable glass-transition temperatures (T_g) and concomitantly photoinduced switch from glassy plastic to viscoplastic polymer; 2) prominent modulation of viscoplasticity under light illumination at different wavelengths. Regionally selective multiple nanopatterns are conveniently fabricated, presenting angle-dependent structural color images on poly(ethylene terephthalate) (PET) substrates. The flexible, athermal and multiple nanopatterning method has the potential for on-demand fabrication of complex nanopatterns.     

Feature extraction method based on NOFRFs and its application in faulty rotor system with slight misalignment

Nonlinear Dynamics - Fault features extraction method for slight misalignment of rotor systems is researched in this paper. When a rotor system with faults is excited by harmonic inputs, system...     

虚拟震源测深法及其在INDEPTH-3台阵中的应用

基于中美合作项目INDEPTH第3期在青藏高原布设的台站，使用虚拟震源测深法研究青藏高原中部的地壳厚度。结果显示，拉萨地体和羌塘地体的地壳结构存在巨大差异。拉萨地体的地壳厚度大约为57 km，与艾里均衡说预测的地壳厚度基本一致，说明拉萨地体的地壳结构比较简单。羌塘地体的地壳厚度为60~75 km，向北有增厚趋势，明显较艾里均衡说预测的地壳厚，说明羌塘地体地壳结构比较复杂，原因有可能是羌塘地体下存在高温流体和低速带，或者与印度板块岩石圈在班公湖-怒江缝合带以北向下俯冲有关。     

In-chain functionalization through the combination of ring opening copolymerization and oxime “Click” reaction towards X-ray opaque polylactide copolymers

X-ray imaging functionalization of biodegradable polyesters is a great demand and challenge in biomedical applications.In this work,a strategy of in-chain functionalization through the combination of ring opening copolymerization and oxime "Click" postfunctionalization was developed towards X-ray opaque polylactide copolymers.A functionalized cyclic carbonate was first synthesized and used as comonomer of polylactide copolymers,which were subjected to postfunctionalization of oxime "Click" reaction towards iodinated polylactide copolymers.The chemical structure and physical properties of the target products were traced and confirmed.In vitro cytotoxicity evaluation with 3T3-Swiss albino by Alamar blue demonstrated a low cytotoxicity.The X-ray radiopacity was analyzed by Micro-CT and quantified by Hounsfield Units value,which could be tailorable by the feedstock.It is a promising X-ray visible implantable biomaterial in biomedical applications.